{"@context":["https://w3id.org/fdo/context/v1",{"schema":"https://schema.org/","prov":"http://www.w3.org/ns/prov#","fdo":"https://w3id.org/fdo/vocabulary/"}],"@id":"https://fdo.portal.mardi4nfdi.de/fdo/Q792185","@type":"DigitalObject","kernel":{"@id":"https://fdo.portal.mardi4nfdi.de/fdo/Q792185","digitalObjectType":"https://schema.org/ScholarlyArticle","primaryIdentifier":"mardi:Q792185","kernelVersion":"v1","immutable":true,"modified":"2026-01-05T15:47:15Z"},"profile":{"@context":"https://schema.org","@type":"ScholarlyArticle","@id":"https://portal.mardi4nfdi.de/entity/Q792185","name":"Charging of a low-conductivity liquid flowing through a cylindrical pipe with allowance for the finite rate of a surface electrochemical reaction","headline":"Charging of a low-conductivity liquid flowing through a cylindrical pipe with allowance for the finite rate of a surface electrochemical reaction","description":"scientific article; zbMATH DE number 3852695","url":"https://portal.mardi4nfdi.de/entity/Q792185","datePublished":"1983-00-00","author":[{"@id":"https://portal.mardi4nfdi.de/entity/Q792183"},{"@id":"https://portal.mardi4nfdi.de/entity/Q792184"},{"@id":"https://portal.mardi4nfdi.de/entity/Q662109"}],"publisher":[{"@id":"https://portal.mardi4nfdi.de/entity/Q174468"}],"identifier":{"@type":"PropertyValue","propertyID":"doi","value":"10.1007/BF01090510","url":"https://doi.org/10.1007/BF01090510"},"sameAs":["https://doi.org/10.1007/BF01090510"],"comment":"In this paper charging of a low-conductivity liquid flowing through a cylindrical metallic pipe with allowance for the finite rate of surface electrochemical reaction, due to ions of a contaminating impurity dissolved in the liquid, is studied. It is shown that in the initial section of the pipe, a kinetic regime exists and far from the initial section there is a diffusion regime. The rate of the charging process depends on the supply of ions in the surface of the pipe. The current is a function of the velocity of the liquid and tends to a limiting value which depends only on the rate of surface reaction. The theory is confirmed by experiments on the charging of hexane flowing through small- diameter pipes. The current is observed to be saturated in the experiments.","citation":[{"@id":"https://portal.mardi4nfdi.de/entity/Q3859499"},{"@id":"https://portal.mardi4nfdi.de/entity/Q1148065"}]},"provenance":{"prov:generatedAtTime":"2026-01-05T15:47:15Z","prov:wasAttributedTo":"MaRDI Knowledge Graph"}}